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Hybrid Fuel Cell/Supercapacitors stack – SUPERCAPAC

Hybrid supercapacitors/fuel cell stacks

SUPERCAPAC main objective is the direct hybridization of a Polymer Electrolyte Membrane Fuel Cells (PEMFC) with supercapacitors, with the objective to reach a high level of integration by inserting the supercapacitors within the fuel cell stack.<br />Such hybrid electricity generators with power ranging from a few tenths of Watt to a few kW could suit a wide variety of -stationary or mobile- nomad applications.<br />

Improve fuel cell maximum power and lifetime

Electrochemical storage of energy can be done using fuel cells, batteries or supercapacitors. Fuel cells actually do not store energy since this is the role of the hydrogen tank; batteries store chemical energy and ensure its conversion from or into electricity; supercapacitors store only electrical charges. Thus, for long time operation, fuel cells energy density is limited mostly by that of the hydrogen tank and can reach several thousand of kWh/kg. However, their power density remains lower than that of batteries or supercapacitors because it is limited by the maximal flux of hydrogen and (mostly) oxygen that it is possible to supply to the electrodes. Conversely, supercapacitors benefit from excellent specific power values while their energy density is low.<br />Fuel cells and supercapacitors differ also in terms of lifespan and cyclability. Supercapacitors can be considered as robust and thus perfectly mature for applications with security (planes) or working conditions (stop & start systems in cars) constraints. Thanks to steady progress in material design, fuel cells can now reach lifetimes higher than 10000 hours but they are still quite sensitive to frequent startups and shutdowns as well as strong power variations: in the case of transportation application for instance, 2000 hours operation time seems to be a barrier difficult to overcome.<br />Within the framework of the SUPERCAPAC project, we will hybridize a polymer exchange membrane fuel cell stack and supercapacitors in order to improve the fuel cell power density and durability.<br />

The main original aspect of the project lies in the innovative and patented stack architecture that will be used to connect directly in parallel each PEMFC cell to a single supercapacitor. Since the cell voltage always remains under 1.2 Volt, this allows using safe and cheap aqueous electrolyte capacitors, which are also much more stable and reliable than the more usual organic electrolytes at the normal operating temperature (50°C - 80°C) of PEMFC.
In a first step, a hybrid stack using standard (cylindrical) capacitors connected to the cells thanks to external terminals will be designed, built, and tested. In the meantime, flat supercapacitors meant to be inserted in a second stack between two adjacent cells will be developed. This second stack will be built and tested during the second half of the project.
The hybridization will improve the performances of the fuel cell in terms of power density and those of the capacitors in terms of energy density and will thus enlarge their operating and application range. SUPERCAPAC also intend to improve the durability and reliability of fuel cells since the supercapacitors will help limiting the voltage variations to which they are submitted, as well as the reverse currents and local degradations induced by start-up and shut-down cycles.
A close attention will be paid to the fabrication costs, robustness, and simplicity of the hybrid stacks through the careful choice of components, materials and assembling technologies. The hybridization should also allow using less or smaller auxiliaries (DC/DC converter, humidifier, cooling system).

The hybridization will improve the performances of the fuel cell in terms of power density and those of the capacitors in terms of energy density and will thus enlarge their operating and application range. SUPERCAPAC also intend to improve the durability and reliability of fuel cells since the supercapacitors will help limiting the voltage variations to which they are submitted, as well as the reverse currents and local degradations induced by start-up and shut-down cycles.

Such hybrid electricity generators with power ranging from a few tenths of Watt to a few kW could suit a wide variety of -stationary or mobile- nomad applications, such as:
• Silent and non-polluting stationary generators.
• Battery charging systems.
• Low weight and low heat signature portable power sources for the foot soldier.
• Auxiliary power units for various kinds of vehicles.
• Power sources for light aerial, underwater or ground unmanned vehicles.

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SUPERCAPAC is a multidisciplinary project gathering laboratories in the fields of material sciences, (IMN – Institut Jean Rouxel), electrical engineering (GREEN) and mechanical engineering (LEMTA). Its main topic is the direct hybridization of a Polymer Electrolyte Membrane Fuel Cells (PEMFC) with supercapacitors, with the objective to reach a high level of integration by inserting the supercapacitors within the fuel cell stack.

Such hybrid electricity generators with power ranging from a few tenths of watts to a few kW could suit a wide variety of -stationary or mobile- nomad applications, such as:
• Silent and non-polluting stationary generators.
• Battery charging systems.
• Low weight and low heat signature portable power sources for the foot soldier.
• Auxiliary power units for various kinds of vehicles.
• Power sources for light aerial, underwater or ground unmanned vehicles.

The main original aspect of the project lies in the innovative and patented stack architecture that will be used to connect directly in parallel each PEMFC cell to a single supercapacitor. Since the cell voltage always remains under 1.2 V, this allows using safe and cheap aqueous electrolyte capacitors, which are also much more stable and reliable than the more usual organic electrolytes at the normal operating temperature (50°C - 80°C) of PEMFC.

In a first step, a hybrid stack using standard (cylindrical) capacitors connected to the cells thanks to external terminals will be designed, built, and tested. In the meantime, flat supercapacitors meant to be inserted in a second stack between two adjacent cells will be developed. This second stack will be built and tested during the second half of the project.

The hybridization will improve the performances of the fuel cell in terms of power density and those of the capacitors in terms of energy density and will thus enlarge their operating and application range. SUPERCAPAC also intend to improve the durability and reliability of fuel cells since the supercapacitors will help limiting the voltage variations to which they are submitted, as well as the reverse currents and local degradations induced by start-up and shut-down cycles.

A close attention will be paid to the fabrication costs, robustness, and simplicity of the hybrid stacks through the careful choice of components, materials and assembling technologies. The hybridization should also allow using less or smaller auxiliaries (DC/DC converter, humidifier, cooling system).

Project coordination

Olivier Lottin (Fédération Jacques Villermaux (FR))

The author of this summary is the project coordinator, who is responsible for the content of this summary. The ANR declines any responsibility as for its contents.

Partner

IMN Institut des Matériaux Jean Rouxel
FJV Fédération Jacques Villermaux (FR)

Help of the ANR 291,275 euros
Beginning and duration of the scientific project: May 2014 - 36 Months

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